The central dogma of organometallic chemistry. Powell explains the inert gas rule, how to count electrons for different ligand types (terminal vs. bridging carbonyls, allyl, cyclopentadienyl), and the consequences of having 16, 17, or 18 electrons.
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Principles of organometallic chemistry : Powell, P. (Paul), 1936 The central dogma of organometallic chemistry
The book covers a wide range of topics, including: and the consequences of having 16
Perhaps the most valuable section for students is the breakdown of fundamental organometallic reaction steps. Powell categorizes reactions into key types: